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Rhenium(VII) oxide : ウィキペディア英語版
Rhenium(VII) oxide

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Rhenium(VII) oxide is the inorganic compound with the formula Re2O7. This yellowish solid is the anhydride of HOReO3. Perrhenic acid, Re2O7·2H2O, is closely related to Re2O7. Re2O7 is the raw material for all rhenium compounds, being the volatile fraction obtained upon roasting the host ore.〔Hans Georg Nadler "Rhenium and Rhenium Compounds" Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2000. 〕
==Structure==
Crystalline Re2O7 is an inorganic polymer, which consists of alternating octahedral and tetrahedral Re centres. Upon heating, the polymer cracks to give molecular (nonpolymeric) Re2O7. This molecular species closely resembles manganese heptoxide, consisting of a pair of ReO4 tetrahedra that share a vertex, i.e., O3Re-O-ReO3.〔Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.〕

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